有机废水资源化技术--发酵产氢

氢作为一种清洁高效的可再生能源日益受到人们的重视.利用有机废水发酵产氢,既保护环境又可获得氢能,是一条符合可持续发展战略的废水资源化途径,极具发展前景.本文介绍了发酵产氢微生物的种类及其产氢机理,对发酵产氢的影响因素进行了分析;总结了有机废水发酵产氢的研究现状,并探讨了今后的研究方向.     

Effect of selected and non-selected urban waste compost on the initial growth of corn

Brazil produces approximately 242,000 t of waste per day, 76% of it being dumped outdoors and only 0.9% recycled, including composting, which is an alternative still little known in Brazil. In search of a better destination for residues produced by domestic activities, composting stands as a feasible alternative. Organic compost from waste may be used for various purposes, among which are soil recovery, commercial production, pastures, lawns and reforestry and agriculture. However, the quality of the compost determines the growth and the development of plants. The effect of compost made from urban waste on corn plant (Zea mays L.) growth was investigated. Two types of compost were used: the selected compost (SC), produced from organic waste selectively collected; and the non-selected compost (NSC), taken from a 15-year-old cell from the Canabrava land-fill, located in Salvador, Bahia, Brazil (altitude 51 m, 12°22′–13°08′S, 38°08′–38°47′W). Corn was seeded in polyethylene pots, with soil-compost mixing substrate in the proportion of 0, 15, 30, 45 and 60 t ha⁻¹ equivalent doses. Chemical analyses of the compost and growth properties of the plant like chlorophyll content; height and stem diameter; aerial and radicular dry biomasses, were used to evaluate compost quality. Plants cultivated with SC presented a superior gain, being of 52.5% in stem diameter, 71.1 and 81.2% in root and stem biomasses, respectively. Chlorophyl content alterations were observed in plants from treatments using 30 t compost ha⁻¹ dose onwards. Conventional and multivariate statistical methods were used to evaluate these results. The beneficial action of organic compost in plant growth was confirmed with this research.     

Mixing hazard evaluation of organic peroxides with other chemicals

Organic peroxides (POs) have been widely used in chemical industries as initiators of polymerization, hardening or bridge formation agents, and they are known for its self-reactive and also mixing hazard characteristics when mixed with other chemicals such as acids and alkalis. It is the purpose of this investigation to propose a simple but useful evaluation flow of mixing hazards of POs with other chemicals using conventional experimental techniques such as a glass test tube test, Dewar vessel test and DSC is proposed. 7 kinds of POs (DEPD, THP, TBEH, TBTC, MEKPO, DTBP, THHP) were mixed with sulfuric acids with various concentration, sodium hydroxide solutions, -iron(III) oxide and acrylonitrile (AN).

Based on the proposed evaluation flow the testing results were classified into 4 ranks due to the hazard criteria. Futhermore DEPD/acrylonitrile mixtures were investigated in more detail and the influences of the mixing ratio and the stirring speed were discussed.     

ClO2去除废水中石油类污染物的研究

就如何使用ClO2和O3对水中石油类污染物氧化去除进行了研究，确定了最佳反应时间、pH和氧化剂用量对去除率的影响。ClO2的最佳投加量应为有机物总量的1．5倍，反应时间可控制在20min上。ClO2处理pH5．0～6．5溶液时的去除效果最好。同时进行了O3的对照实验。分析了ClO2和O3在水处理应用中的优缺点。     

Experimental investigation of a 250-kW turbine organic Rankine cycle system for low-grade waste heat recovery

An organic Rankine cycle (ORC) is generally used for converting low-grade heat into electricity. In this study, an extensive literature survey was conducted to identify current research gaps on experimental ORC systems. Specifically, there is limited experimental data and limited details on thermal and expander efficiencies of ORC systems. In order to address these gaps, the objective of this study included developing a turbine ORC with a power output exceeding 50 kW and thermal efficiency exceeding 8% for a heat source temperature < 120°C. The experimental results indicated that the system achieved a net power output of 242.5 kW and a thermal efficiency of 8.3% (the highest value for a turbine ORC system for the heat source temperature below 120°C). Thus, the study addressed the gaps identified in the research area of ORCs.     

地下停车库空气污染物排放实测研究

通过对上海市某商业地下停车库库内及排风管道的连续监测,获得了CO、NO、非甲烷总烃(NMHC)、PM10等空气污染物浓度数据。结果表明:(1)地下停车库的休息日车流量明显大于工作日,且工作日小时车流与车位比为20%~50%、休息日小时车流与车位比为20%~80%。(2)总体上,地下停车库内CO、NO、NMHC浓度呈明显变化规律,营业时间现峰值,非营业时间现谷值;地下停车库内CO、NO、NMHC变化规律和车库排风中具有较好的一致性。(3)车库排风中污染物浓度水平均低于地下停车库内。(4)营业时间的CO、NO、NMHC小时浓度平均值明显增大,约为非营业时间的2.42~3.67倍。(5)单车次CO、NOX、NMHC排放量最大值分别为0.855、0.070、0.214g/(辆·次)。(6)营业时间,除地下停车库内CO外,NO、PM10的8h时间加权平均值符合《工作场所有害因素职业接触限值化学有害因素》(GBZ 2.1—2007,其中未规定NMHC)中时间加权平均容许浓度(PC-TWA);地下停车库内CO出现33.3%的超标频率,最大占标率104%。     

The rise of glyphosate and new opportunities for biosentinel early‐warning studies

Glyphosate has become the most commonly used herbicide worldwide and is reputedly environmentally benign, nontoxic, and safe for use near wildlife and humans. However, studies indicate its toxicity is underestimated and its persistence in the environment is greater than once thought. Its actions as a neurotoxin and endocrine disruptor indicate its potential to act in similar ways to persistent organic pollutants such as the organochlorines dichlorodiphenyltrichloroethane (DDT) and dioxin. Exposure to glyphosate and glyphosate‐based herbicides for both wildlife and people is likely to be chronic and at sublethal levels, with multiple and ongoing exposure events occurring in urban and agricultural landscapes. Despite this, there has been little research on the impact of glyphosate on wildlife populations, and existing studies appear in the agricultural, toxicology, and water‐chemistry literature that may have limited visibility among wildlife biologists. These studies clearly demonstrate a link between chronic exposure and neurotoxicity, endocrine disruption, cell damage, and immune suppression. There is a strong case for the recognition of glyphosate as an emerging organic contaminant and substantial potential exists for collaborative research among ecologists, toxicologists, and chemists to quantify the impact of glyphosate on wildlife and to evaluate the role of biosentinel species in a preemptive move to mitigate downstream impacts on people. There is scope to develop a decision framework to aid the choice of species to biomonitor and analysis methods based on the target contaminant, spatial and temporal extent of contamination, and perceived risk. Birds in particular offer considerable potential in this role because they span agricultural and urban environments, coastal, inland, and wetland ecosystems where glyphosate residues are known to be present.     

基于高频AQI数据的关中城市群空气污染规律探索

基于高频分时AQI及各污染物浓度数据,本文使用"AQI小时指数"、首要污染物等进行统计分析并建立VAR模型对关中城市群空气污染的总体情况、日内波动规律以及城市间空气污染的关联规律做了不同层次的挖掘。研究结果表明:(1)关中城市群的空气质量整体较差,春、冬季空气污染程度明显大于夏季,空气污染的"季节效应"和"集簇性"明显,且主要表现为颗粒物污染。(2)空气质量的日内波动规律在春、冬两季表现为下半天优于上半天,夏季夜间优于白天。但在不考虑四季AQI小时指数图"相位"差异的情况下,四季空气污染的日内波动呈现出明显的相似性。(3)各城市空气污染存在明显的关联规律。城市群内一个城市空气污染的恶化会加剧其他城市的空气污染,并且对其他城市空气污染的影响峰值会在24小时之内出现,且该影响会随着空间和时间尺度的增大而逐步衰减。     

广州白云国际机场飞机大气污染物排放分析

根据收集到的2008-2012年广州白云国际机场航班起降次数，参考《珠江三角洲非道路移动源排放清单开发》飞机污染物估算方法及排放因子，计算出此期间机场飞机大气污染物排放量，并与2010-2012年广州市机动车污染物排放情况对比。结果表明：飞机大气污染物排放量随客运量的增长呈逐年上升趋势，而与机动车排放相比，飞机大气污染物排放量较小，故现阶段仍应以机动车作为移动源污染控制的重点。     

燃煤电厂超低排放气态污染物监测技术综述

介绍了燃煤电厂超低排放气态污染物监测系统的采样系统和分析单元,分析了其各自的优缺点。对稀释抽取式、冷干抽取式和热湿抽取式3种采样方法,以及非分散红外吸收法(NDIR)、非分散紫外吸收法(NDUV)、紫外差分吸收法(DOAS)、紫外荧光法(UVF)和化学发光法(CL)5种分析方法进行对比。结果表明,冷干抽取式+紫外差分法以及稀释抽取式+紫外荧光法+化学发光法可以较好地符合燃煤电厂超低排放监测的要求。